Preparation of Colloids – Class 12 | Chapter – 5 | Surface Chemistry | Chemistry Short Notes Series PDF for NEET & JEE

Preparation of Colloids: Colloids preparation method depends on the specific type of colloid desired and the nature of the colloidal particles and the continuous medium. Proper control of preparation parameters is crucial to obtain stable and well-defined colloids with desired properties for various applications.

Preparation of Colloids

Colloids can be prepared using various methods depending on the type of colloid desired. Here are some common methods for preparing colloids:

  • Dispersion or Mechanical Disintegration: This method involves physically breaking down larger particles into colloidal size by mechanical means. For example:
    • Grinding: Solid substances are ground into fine particles using a mortar and pestle or a ball mill.
    • Ultrasonication: High-frequency ultrasonic waves are used to break down larger particles into colloidal size.
  • Condensation or Chemical Methods: In these methods, chemical reactions are employed to produce colloidal particles. Some examples include:
    • Precipitation: Colloidal particles are formed by adding a precipitating agent to a solution, leading to the formation of colloidal particles. For example, silver chloride sol can be prepared by adding silver nitrate to sodium chloride solution.
    • Reduction: Metal colloids can be obtained by reducing metal salts with a reducing agent. For instance, colloidal gold sol can be prepared by reducing gold chloride with a reducing agent like sodium citrate.
    • Hydrolysis: Colloids of metal hydroxides can be obtained by the hydrolysis of metal salts. For example, ferric hydroxide sol can be prepared by the hydrolysis of ferric chloride.
  • Emulsification: This method is used to prepare emulsions, where one liquid is dispersed as droplets in another immiscible liquid. Emulsification is often achieved by vigorous shaking or stirring, or by using emulsifying agents or surfactants.
  • Micellar Method: Micellar colloids are prepared by dissolving surfactant molecules in a liquid medium. When the concentration of surfactant exceeds the critical micelle concentration (CMC), micelles form spontaneously.
  • Gelation: Colloidal gels can be formed by cooling certain colloidal solutions or by adding a gelling agent. The gel network traps colloidal particles, forming a stable gel.
  • Electrodispersion: In this method, an electric field is applied to a suspension containing charged particles, leading to their dispersion into the medium.
  • Dialysis: Dialysis is a method used to remove excess ions or small molecules from a colloidal solution. By placing the colloidal solution in a dialysis bag or membrane, the smaller molecules diffuse out, leaving behind the colloidal particles.

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By Team Learning Mantras