Classification of Colloids – Class 12 | Chapter – 5 | Surface Chemistry | Chemistry Short Notes Series PDF for NEET & JEE

Classification of Colloids: Classification of colloids is important for various applications, as different types of colloids exhibit unique properties and behaviors. For example, the stability and interactions of colloidal particles depend on their charge and the nature of the continuous medium, which can significantly influence their applications in industries ranging from pharmaceuticals and food to environmental remediation and nanotechnology.

Classification of Colloids

Colloids can be classified based on the phase of the dispersed particles and the continuous medium. The primary classifications of colloids are as follows:

  • Based on Particle Phase:
    • Solid Colloids (Sols): In solid colloids, solid particles are dispersed in a liquid medium. These colloids are also known as sols. Examples include colloidal gold sol and sols of metal hydroxides.
    • Liquid Colloids (Emulsions): In liquid colloids, liquid droplets are dispersed in another immiscible liquid medium. These colloids are known as emulsions. Examples include milk (oil-in-water emulsion) and mayonnaise (water-in-oil emulsion).
    • Gas Colloids (Aerosols): In gas colloids, small gas particles are dispersed in a liquid or solid medium. Aerosols are an example of gas colloids. Atmospheric aerosols and fog are common examples.
  • Based on Continuous Medium:
    • Lyophilic (Solvent-Loving) Colloids: In lyophilic colloids, the dispersed phase has a strong affinity for the continuous medium. The colloidal particles are stable and readily disperse in the solvent. These colloids do not require the addition of stabilizing agents. Examples include starch sols and gum arabic sols.
    • Lyophobic (Solvent-Fearing) Colloids: In lyophobic colloids, the dispersed phase has a weak affinity for the continuous medium. The colloidal particles are relatively unstable and require the addition of stabilizing agents to prevent coagulation. Examples include metal sulfides and metal hydroxide sols.
  • Based on Particle Charge:
    • Positive or Cationic Colloids: Colloidal particles that carry a net positive charge due to the presence of cations (positively charged ions) on their surfaces.
    • Negative or Anionic Colloids: Colloidal particles that carry a net negative charge due to the presence of anions (negatively charged ions) on their surfaces.
    • Nonionic Colloids: Colloidal particles that do not carry a net charge on their surfaces. These colloids are stabilized by other mechanisms, such as steric hindrance or van der Waals forces.
  • Based on Particle Size:
    • Micellar Colloids: Micellar colloids consist of surfactant molecules forming micelles in a liquid medium. Micelles are self-assembled structures where the hydrophobic tails of surfactant molecules are shielded from the surrounding medium by their hydrophilic heads.
    • Macromolecular Colloids: Macromolecular colloids consist of large molecules, such as proteins or synthetic polymers, dispersed in a liquid medium.

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By Team Learning Mantras