Solubility – Class 12 | Chapter – 2 | Chemistry Short Notes Series PDF for NEET & JEE
Solubility: Solubility refers to the ability of a substance (the solute) to dissolve in a particular solvent, usually water. It is defined as the maximum amount of solute that can be dissolved in a given amount of solvent at a specific temperature and pressure.
The solubility of a substance is often expressed in terms of grams of solute per 100 grams of solvent (g/100g) or in terms of grams of solute per liter of solution (g/L) at a specific temperature and pressure. The solubility of a substance is an important property in fields such as chemistry, biochemistry, and environmental science.
The solubility of a substance depends on several factors, including:
- Nature of the solute and solvent: The solubility of a substance depends on the chemical nature of both the solute and solvent. For example, polar solutes tend to dissolve in polar solvents, while nonpolar solutes tend to dissolve in nonpolar solvents.
- Temperature: In general, the solubility of solids in liquids increases with temperature, while the solubility of gases in liquids decreases with temperature. This is because increasing the temperature increases the kinetic energy of the solute particles, making it easier for them to break away from the crystal lattice and dissolve in the solvent.
- Pressure: The solubility of gases in liquids is also affected by pressure. Increasing the pressure increases the solubility of gases in liquids, while decreasing the pressure decreases the solubility.
- pH: The solubility of some substances is also affected by the pH of the solution. For example, some acids and bases are more soluble in acidic or basic solutions, respectively.
Types of Solubility
There are two main types of solubility:
- Miscible: Two substances are miscible if they are able to mix together in all proportions to form a homogeneous solution. For example, ethanol and water are miscible because they can be mixed together in any proportion to form a homogeneous solution.
- Immiscible: Two substances are immiscible if they are unable to mix together to form a homogeneous solution. Instead, they form separate layers. For example, oil and water are immiscible and will separate into two distinct layers when mixed together.
In addition to these two main types, there are other types of solubility that can be observed:
- Partially miscible: Two substances are partially miscible if they can mix together, but only up to a certain point. Beyond that point, they will form separate layers. For example, water and cyclohexane are partially miscible, meaning that they can mix together up to a certain point, but beyond that point, they will separate into two distinct layers.
- Hydrate solubility: Some substances, particularly salts, have the ability to form hydrates with water molecules. The solubility of these substances can be affected by the presence or absence of water molecules in the crystal lattice. For example, anhydrous copper sulfate is not very soluble in water, but when it forms a hydrate with five water molecules, it becomes much more soluble.
- Supersaturation: A supersaturated solution is one in which more solute has been dissolved than is theoretically possible at a particular temperature and pressure. Supersaturated solutions are often unstable and can be made to crystallize by adding a small amount of solute or by disturbing the solution in some way.
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